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Continuum absorption by water vapor

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Another theory, "third-order linear absorption," in which pairs of water molecules cooperatively absorb photons while both molecules undergo transitions in internal The infrared spectrum of water vapor is made up of strongly absorbing bands, consisting of large numbers of individual spectral lines, interspersed by “windows” with much weaker absorption. The absorption in these windows is dominated not by spectral lines, but by the so‐called water vapor continuum, a slowly varying component of absorption that Water vapor plays the dominant role in the propagation of mm and THz electromagnetic waves in the atmosphere, since it has several thousand rotational absorption lines from the mm wave range through the terahertz region up to 5 THz. Also, oxygen gas has a cluster of approximately 25 overlapping lines at 60 GHz and a single line at 120 GHz. The pure water-vapor continuum absorption in the 2.88 to 5.18μm spectral region has been measured using a Fourier-transform infrared spectrometer at a resolution of 0.1cm−1. The water vapour continuum is characterised by absorption that varies smoothly with wavelength, from the visible to the microwave. It is present within the rotational and vibrational–rotational bands of water vapour, which consist of large numbers of narrow spectral lines, and in the many ‘windows’ between these bands.

Weakly Interacting Molecular Pairs: Unconventional Absorbers of

The accurate modeling of continuum absorption is crucial for the so-called window regions of the spectrum, the relatively transparent regions between lines. The window regions in the microwave are of critical importance for Earth remote sensing and data assimilation. The conventional description of water vapor infrared absorption is applied, in which the absorption is modeled in two parts consisting of local line absorption and the remaining residual absorption, which has become known as the water vapor continuum. This water vapor continuum consists of distinct water-water, water-nitrogen, and water-oxygen continua.

Continuum absorption by water vapor

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Water vapor plays the dominant role in the propagation of mm and THz electromagnetic waves in the atmosphere, since it has several thousand rotational absorption lines from the mm wave range through the terahertz region up to 5 THz. Also, oxygen gas has a cluster of approximately 25 overlapping lines at 60 GHz and a single line at 120 GHz. Infrared continuum absorption by atmospheric water vapor in the 8-12-microm window. Roberts RE, Selby JE, Biberman LM. We have carried out a detailed analysis of several long pathlength transmission measurements in the 8-12-microm atmospheric window in order to determine the extinction coefficient due to the water vapor continuum. The pure water-vapor continuum absorption in the 2.88 to 5.18μm spectral region has been measured using a Fourier-transform infrared spectrometer at a resolution of 0.1cm−1. The water vapor continuum absorption spectrum is retrieved using the known absorption in the 2500 cm−1 region as a reference point. It is shown that the continuum absorptions in four windows differ Water vapor continuum absorption coeffi cient C (v) at T= 296 K as a function of frequency v and wavelength X in the 8-30-gm region; most recent data of Burch 21,24 (-). The solid line represents a linear regression (described in text) to all Burch's recent water vapor data for the 8-30-,um region. The pure water-vapor continuum absorption in the 2.88 to 5.18μm spectral region has been measured using a Fourier-transform infrared spectrometer at a resolution of 0.1cm−1.

Continuum absorption is explained semi-empirically as the overlap of absorption due to many absorption lineswith centers far from the continuum region. A good example occurs in the 10- μm windowregion, where continuum absorption by water vaporcan be particularly important. Compareband absorption, line absorption. 9 Continuum absorption by water vapor is defined as any observed absorption by water vapor not attributable to the Lorentz line contribution within 25 cm-1 of each line. It has been suggested that it results from the accumulated absorption of the distant wings of lines in the far infrared. This absorption is caused by collision Each atmospheric gas has a specific absorption/emission spectrum – its own signature. Continuum absorption by water vapor is defined as any observed absorption by water vapor not attributable to the Lorentz line contribution within 25 cm-1 of each line.
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At present, the physical mechanisms of the water vapor continuum absorption are still a matter of discussion.

Response Continuum, Washington DC, 2005 (poster) (awarded). 135.
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PPPS. This history of infra-red astronomy shows that we have to get up above 3 km in a dry part of the world in order to see infra-red light from outer space. water vapor continuum defined as any observed absorption due to water vapor not attributable to the Lorentz line contribution(a) within 25 cm-1 of each line, a water vapor monomer line shape formalism was semi-empirically derived and consistently applied to all water vapor lines from the microwave to the shortwave.


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DEMILITARIZATION warheads, RF-warheads and computational continuum dynamics. absorption of laser light. LIF can e.g.